Yes, you absolutely will need to change the algorithm setting on the charger or you will slowly kill those new batteries. The 8v vs 12v is not relevant, as it’s still a 72v pack and it’s a 72V charger. The problem is the battery chemistry is different, way different. Those Polaris 8V batteries are gel cells. the Duracell SLI31MDC s a Flooded Lead Acid battery (aka “FLA”). Gel batteries and FLAs have very different charging profiles, the short explanation is that charging FLAs with a gel setting will result in undercharging that, besides simply not giving you 100% of your battery capability, will cause the more rapid forming of a non-conductive layer on the submerged lead plates, as this forms, the battery becomes “weaker” - less able to store and pass electricity and will fail prematurely,
You are going to need to chock the rear wheels, and put the front end on jack stands, and watch the blink code on the charger as you first power it up. You may be able to see what you need by taking off one of the front wheels.
Being government surplus and possibly having been purchased w/ different requirements than what the stock civilian models come as, we can’t be 100% sure if the charger still has the typical algorithms installed, I would recommend you find out what it’s set to and check a couple charts to see what matches, from that you can kind of pick the one you need to switch it to.
If it’s the vanilla gem package, factory setting would be 14 maybe switched to 24. For that, switch it to 32 for the FLAs you bought. The battery pictures you posted show a date code that matches the model year of the vehicle, so hopefully it’s the stock charger programming and no one dicked with it.
If you find that it’s set to something else, there are so many possibilities, best to just post it and we can take some stabs at it then.
Links for the PDFs on how to check / change algorithms and the stock GEM programming are below.
User manual:
https://support.delta-q.com/hc/en-us/article_attachments/360012713231
Stock GEM algorithms list / instructions:
https://support.delta-q.com/hc/en-us/article_attachments/360012712932
BTW- those SLI31MDCs are really good batteries for the coin. Built by EastPenn Deka in the US and they use virgin lead rather than recycled. You need to check the water periodically - depends how much you use it. Once every week or other week until you get a feel for the rate it drops by. Avoid the Trojan flooded battery profiles if you can, they can be pretty brutal on mere mortal batteries. Trojan batteries are kind of in a class by themselves, there’s over 50% more lead in them.